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Shifted excitation Raman difference spectroscopy: A promising tool for the investigation of soil

L.S. Theurer, M. Maiwald, B. Sumpf

Published in:

Eur. J. Soil Sci., vol. 72, no. 1, pp. 120-124 (2021).

Abstract:

In this paper we demonstrate shifted excitation Raman difference spectroscopy (SERDS) for soil analysis as a proof of concept. Confocal Raman microscopy is performed for sample analysis as well as for qualitative comparison with our SERDS experiments. Raman spectra of a soil sample show huge background signals, which mask weak Raman peaks. SERDS clearly separates the Raman signals from background signals with a 10-fold improvement of the signal-to-background noise ratio. Thus, besides hydroxyapatite, additional Raman bands from quartz and feldspar could be extracted. The results demonstrate SERDS as a promising tool for soil analysis.

Lasers Sensors Lab, Ferdinand-Braun-Institut, Leibniz-Institut für Höchstfrequenztechnik, Gustav-Kirchhoff-Str. 4, 12489 Berlin, Germany

Keywords:

diode laser, optical sensor, phosphate, Raman spectroscopy, soil analysis

Copyright © 2019 British Society of Soil Science. Personal use of this material is permitted. However, permission to reprint/republish this material for advertising or promotional purposes or for creating new collective works for resale or redistribution to servers or lists, or to reuse any copyrighted component of this work in other works must be obtained from British Society of Soil Science.

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